Arrested B-H activation en route to installation of a PBP pincer ligand on ruthenium and osmium
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Hill, Anthony
McQueen, Caitlin
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American Chemical Society
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The reaction of HB(NCH2PPh2)2C 6H4-1,2 with MCl2(PPh3)3 (M = Ru, Os) affords the six-coordinate σ-borane complexes [MCl 2(PPh3){σ-BH-κ2-P,P′- HB(NCH2PPh2)2-C6H4}], in which the B-H bond remains intact while coordinated to the metal center. Replacemen
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Organometallics
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2037-12-31
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