A homoleptic hydrotris(methimazolyl)borate complex of titanium

Hill, Anthony; Smith, Matthew

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A homoleptic hydrotris(methimazolyl)borate complex of titanium

Date

2007

Authors

Hill, Anthony

Smith, Matthew

Publisher

Royal Society of Chemistry

Abstract

The reaction of [Ti2(-Cl)2(thf)2(η- C8H8)2] with Na[HB(mt)3] (mt = methimazolyl) provides the unusual salt [Ti{HB(mt)3} 2][TiCl4(thf)2], the cation of which features homoleptic TiIIIS6 coordination.