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C-H and C-F coordination of arenes in neutral alkaline earth metal complexes

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dc.contributor.authorMcMullen, Jacob
dc.contributor.authorEdwards, Alison J
dc.contributor.authorHicks, Jamie
dc.date.accessioned2024-03-05T01:38:05Z
dc.date.issued2021
dc.date.updated2022-10-16T07:26:29Z
dc.description.abstractA series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feature rare group 2 metal⋯aromatic interactions, such as the η6-coordination of benzene and ‘agostic-like’ C-H coordination, the latter previously unseen in neutral Mg and Ca complexes.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.urihttp://hdl.handle.net/1885/315719
dc.language.isoen_AUen_AU
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DE190100524en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP210100454en_AU
dc.rights© 2021 The authorsen_AU
dc.sourceDalton Transactionsen_AU
dc.titleC-H and C-F coordination of arenes in neutral alkaline earth metal complexesen_AU
dc.typeJournal articleen_AU
local.bibliographicCitation.issue25en_AU
local.bibliographicCitation.lastpage8689en_AU
local.bibliographicCitation.startpage8685en_AU
local.contributor.affiliationMcMullen, Jacob, College of Science, ANUen_AU
local.contributor.affiliationEdwards, Alison J, Australian Centre for Neutron Scatteringen_AU
local.contributor.affiliationHicks, Jamie, College of Science, ANUen_AU
local.contributor.authoruidMcMullen, Jacob, u6042838en_AU
local.contributor.authoruidHicks, Jamie, u1079831en_AU
local.description.embargo2099-12-31
local.description.notesImported from ARIESen_AU
local.identifier.absfor340200 - Inorganic chemistryen_AU
local.identifier.ariespublicationa383154xPUB20036en_AU
local.identifier.citationvolume50en_AU
local.identifier.doi10.1039/d1dt01532jen_AU
local.identifier.scopusID2-s2.0-85108870377
local.identifier.thomsonIDWOS:000664225200001
local.publisher.urlhttps://pubs.rsc.org/en_AU
local.type.statusPublished Versionen_AU

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