Stille/Diels-Alder reaction sequences: diversity-oriented access to novel steroids

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Sunnemann, Hans Wolf
Hofmeister, Anja
Magull, Jörg
Banwell, Martin
de Meijere, Armin

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American Chemical Society

Abstract

An efficient, diversity-oriented approach to novel steroid analogues possessing a C-5β configuration begins with the Stille cross-coupling of enantiomerically pure cycloalkenylstannane trans-2 and enol triflate 3. The resulting diene trans-4 engages in D

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Organic Letters

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Restricted until

2037-12-31