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Stille/Diels-Alder reaction sequences: diversity-oriented access to novel steroids

Date

Authors

Sunnemann, Hans Wolf

Hofmeister, Anja

Magull, Jörg

Banwell, Martin

de Meijere, Armin

Publisher

American Chemical Society

Abstract

An efficient, diversity-oriented approach to novel steroid analogues possessing a C-5β configuration begins with the Stille cross-coupling of enantiomerically pure cycloalkenylstannane trans-2 and enol triflate 3. The resulting diene trans-4 engages in D

Keywords

Keywords: alkadiene; cross linking reagent; cycloalkane derivative; mesylic acid derivative; organometallic compound; stannane; steroid; tin derivative; trifluoromethanesulfonic acid; unclassified drug; article; chemical model; chemistry; cyclization; stereoisomeri

URI

http://hdl.handle.net/1885/24028

Collections

ANU Research Publications

Source

Organic Letters

Type

Journal article

DOI

10.1021/ol062878m

Restricted until

2037-12-31

Downloads

File

Description

01_Sunnemann_Stille/Diels-Alder_reaction_2007.pdf (94.36 KB)

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