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Synthesis, structure and optical limiting properties of organoruthenium-chalcogenide clusters

Date

Authors

Lockhart-Gillett, Bryce

Samoc, Marek

Skelton, Brian

Tolhurst, Vicki-Anne

White, Allan

Wilson, Adele

Yates, Brian F

Humphrey, Mark

Publisher

Elsevier

Abstract

Treatment of Ru3(CO)12 with Ph3PS affords the compounds [Ru3(μ3-S)2(CO)9 - n(PPh3)n] (n = 1 (1a), 2 (2a)) and [Ru3(μ3-S)(μ3-CO)(CO)7(PPh3)2] (3a) as the major products. Single crystal X-ray diffraction studies of [Ru3(μ3-S)2(CO)8(PPh3)] and [Ru3(μ3-S

Keywords

Keywords: Complexation; Molecular structure; Optical properties; Organometallics; Reaction kinetics; Single crystals; Synthesis (chemical); X ray diffraction analysis; Cluster compounds; Ligand displacement; Optical limiting properties; Z-scan technique; Ruthenium Chalcogenide; Cluster; Optical power limiting; Ruthenium; X-ray structure

URI

http://hdl.handle.net/1885/81047

Collections

ANU Research Publications

Source

Journal of Organometallic Chemistry

Type

Journal article

DOI

10.1016/j.jorganchem.2004.12.018

Restricted until

2037-12-31

Downloads

File

Description

01_Humphrey_Synthesis,_structure_and_2005.pdf (317.47 KB)