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Synthesis and non-linear optical properties of ( η 5 -pentaphenylcyclopentadienyl)dicarbonylruthenium(II) σ-alkenyl complexes

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Date

2005

Authors

Humphrey, Paul A
Turner, Peter
Masters, Anthony Frederick
Field, Leslie D
Cifuentes, Marie
Asselberghs, Inge
Persoons, Andre Pierre
Samoc, Marek
Luther-Davies, Barry
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

The complexes [Ru{(Z)-HCCHPh}(CO)2(η5-C 5Ph5)] (1) and [Ru{(Z)-HCCHC6H 4NO2}(CO)2(η5-C 5Ph5)] (2) have been synthesized and their identity confirmed by single-crystal X-ray diffraction studies. Reaction of 2 with PMe2Ph and Me3NO in tetrahydrofuran affo

Description

Keywords

Keywords: alkenyl group; ruthenium derivative; tetrahydrofuran; article; chemical reaction kinetics; complex formation; cyclic potentiometry; oxidation kinetics; physical chemistry; X ray diffraction Alkenyl; Crystal structures; Cyclic voltammetry; Non-linear optics; Pentaphenylcyclopentadienyl; Ruthenium

Citation

URI

http://hdl.handle.net/1885/76563

Collections

ANU Research Publications

Source

Inorganica Chimica Acta

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/j.ica.2004.09.045

Restricted until

2037-12-31

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01_Humphrey_Synthesis_and_non-linear_2005.pdf (417.09 KB)

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