Metallathiirenes. 5. Bis- and tris(methimazolyl)borato thiocarbamoyl complexes of molybdenum(II)

Foreman, Mark; Hill, Anthony; Tshabang, Never; White, Andrew G; Williams, David

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Metallathiirenes. 5. Bis- and tris(methimazolyl)borato thiocarbamoyl complexes of molybdenum(II)

Date

2003

Authors

Foreman, Mark

Hill, Anthony

Tshabang, Never

White, Andrew G

Williams, David

Publisher

American Chemical Society

Abstract

The synthesis of the molybdenum thiocarbamoyl complexes was presented. The complexes were obtained from the reactions of [Mo(η2-SCNMe 2)Cl(CO)2(tmeda)] and Na[HnB(mt) 4-n] or via reactions of the salts Na[Mo(CO)2+n{H nB(mt)4-n}] with Me2NCSCl. For n=2, t