Bis(methimazolyl)silyl Complexes of Ruthenium

Hill, Anthony; Neumann, Horst; Wagler, Jorg

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Bis(methimazolyl)silyl Complexes of Ruthenium

Date

2010

Authors

Hill, Anthony

Neumann, Horst

Wagler, Jorg

Publisher

American Chemical Society

Abstract

The new bis(methimazolyl)silane PhSiH(mt)2 (mt = methimazolyl), obtained from methimazole (Hmt) and phenyldichlorosilane, reacts with [Ru(η4-C8H12)(η6-C 8H10)] in refiuxing tetrahydrofuran to provide the cis and trans isomers of [Rui{k3Si,S,S-SiPh(mt)2}