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The polarity origin of the bipolar resistance switching behaviors in metal/ La0.7 Ca0.3 MnO3 /Pt junctions

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Authors

Yang, Rui
Li, Xiaomin
Yu, Weidong
Gao, Xiangdong
Shang, D S
Liu, Xinjun
Cao, Xun
Wang, Qun
Chen, Lidong

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American Institute of Physics (AIP)

Abstract

Bipolar resistance switching behaviors in the M/ La0.7 Ca 0.3 MnO3 /Pt (M=Pt, Ag, Cu, Al, Ti, and W) junctions were investigated. We found that the switching polarities of the junctions for M=Pt, Ag, and Cu were opposite to those for M=Al, Ti, and W. This phenomenon was attributed to the different Gibbs free energy of the metal oxide formation. Based on Auger electron spectroscopy measurement of the M/ La0.7 Ca0.3 MnO3 interfaces, the switching mechanisms were further discussed in terms of metal electrode redox reaction for M=Al, Ti, and W and oxygen vacancy generation/annihilation in the La0.7 Ca 0.3 MnO3 film for M=Pt, Ag, and Cu, respectively.

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Applied Physics Letters

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2037-12-31