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Chemoenzymatic Access to Versatile Epoxyquinol Synthons

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dc.contributor.authorPinkerton, David
dc.contributor.authorBanwell, Martin
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-07T22:16:12Z
dc.date.issued2009
dc.date.updated2016-02-24T09:51:28Z
dc.description.abstractThe enantiomerically pure and readily available metabolites 10-12 have been converted over four simple steps Into the epoxyquinol derivatives 22-24, respectively. Compounds 23 and 24 or their Immediate precursors have been exploited In efficient total syntheses of (-)-bromoxone (ent-1), (-)-epiepoformin (ent-2), (-)-harveynone (4), (+)-panepophenanthrin (6), and (+)-hexacyclinol (9).
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/1885/17924
dc.publisherAmerican Chemical Society
dc.sourceOrganic Letters
dc.subjectKeywords: bromoxone; cyclohexene derivative; epiepoformin; epoxide; fused heterocyclic rings; harveynone; hexacyclinol; hydroquinone derivative; panepophenanthrin; phenanthrene derivative; polycyclic hydrocarbon; article; chemistry; conformation; stereoisomerism; s
dc.titleChemoenzymatic Access to Versatile Epoxyquinol Synthons
dc.typeJournal article
local.bibliographicCitation.issue19
local.bibliographicCitation.lastpage4293
local.bibliographicCitation.startpage4290
local.contributor.affiliationPinkerton, David, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBanwell, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidPinkerton, David, u3968575
local.contributor.authoruidBanwell, Martin, u9500594
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationu2544221xPUB3
local.identifier.citationvolume11
local.identifier.doi10.1021/ol9016657
local.identifier.scopusID2-s2.0-70350140382
local.identifier.thomsonID000269989100011
local.type.statusPublished Version

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