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A chemoenzymatic synthesis of the styryllactone (+)-goniodiol from naphthalene

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Date

2002

Authors

Banwell, Martin
Coster, Mark
Karunaratne, Ochitha
Smith, Jason A

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The enantiomerically pure cis-1,2-diol 2, which is obtained by microbial oxidation of naphthalene, has been converted, via a sequence of reactions including oxidative C-C bond cleavage, decarbonylation and ring-closing metathesis steps, into the natural product (+)-goniodiol (1).

Description

Keywords

Keywords: Carbonylation; Chemical bonds; Chromatography; Enzyme kinetics; Hydroxylation; Microbiology; Molecular structure; Oxidation; Synthesis (chemical); Chemoenzymatic synthesis; Decarbonylation; Goniodiol; Microbial oxidation; Ring closing metathesis; Styrylla

Citation

URI

http://hdl.handle.net/1885/73000

Collections

ANU Research Publications

Source

Journal of the Chemical Society, Perkin Transactions 1

Type

Journal article

Book Title

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