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A simple halide and silver-free synthesis of Echavarren's catalyst directly from gold powder

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Date

2018

Authors

Albayer, Mohammad
Corbo, Robert
Hill, Anthony
Dutton, Jason L

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

An expedient procedure is reported for the preparation of the synthetically valuable Au(I) complex [Au(MeCN)(PtBu2C6H4Ph-2)][BF4] (Echavarren's catalyst) directly from gold powder using [NO][BF4] in acetonitrile. The synthetic method obviates the potential presence of silver or halide impurities that follow from the tedious conventional synthesis, and have otherwise been shown to moderate catalyst performance.

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Keywords

Citation

URI

http://hdl.handle.net/1885/216851

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

DOI

10.1039/C7DT04494A

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10.1039_C7DT04494A.pdf (339.5 KB)

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