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Solvent-induced syntheses of 2D/3D [AgSCN] n -based supramolecular isomers with unusual topologies: structural, theoretical and nonlinear optical studies

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Li, Jianghua
Meng, Suci
Zhang, Jinfang
Song, Yinglin
Huang, Zhipeng
Zhao, Huajian
Wei, Hongyang
Huang, Wenjiang
Cifuentes, Marie
Zhang, Chi

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Royal Society of Chemistry

Abstract

Reactions of hexamethylenetetramine (hmt) and AgSCN in different solvents generated three distinct [AgSCN] n-based coordination polymers (CPs): [Ag(1,3-μ 2-SCN)(μ 2-hmt)] n (1), {[Ag(1,1,3-μ 3-SCN)] 2(μ 2-hmt)} n (2) and [Ag(1,1,3-μ 3-SCN)(μ 4-hmt)

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CrystEngComm

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2037-12-31