Templated Rearrangement of Silylated Benzoxazolin-2-ones: A Novel Tridentate (ONO) 2- Chelating Ligand System
Date
2007
Authors
Wagler, Jorg
Hill, Anthony
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Volume Title
Publisher
American Chemical Society
Abstract
The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.
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Keywords: Chelation; Silanes; Silicon compounds; Pentacoordinate silicon; Phenyltrichlorosilane; Silylated benzoxazolin; Thermally rearranges; Ligands
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Organometallics
Type
Journal article
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2037-12-31
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