Templated Rearrangement of Silylated Benzoxazolin-2-ones: A Novel Tridentate (ONO) 2-  Chelating Ligand System

Wagler, Jorg; Hill, Anthony

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Templated Rearrangement of Silylated Benzoxazolin-2-ones: A Novel Tridentate (ONO) 2- Chelating Ligand System

Date

2007

Authors

Wagler, Jorg

Hill, Anthony

Publisher

American Chemical Society

Abstract

The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.