Templated Rearrangement of Silylated Benzoxazolin-2-ones: A Novel Tridentate (ONO) 2- Chelating Ligand System

Date

2007

Authors

Wagler, Jorg
Hill, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.

Description

Keywords

Keywords: Chelation; Silanes; Silicon compounds; Pentacoordinate silicon; Phenyltrichlorosilane; Silylated benzoxazolin; Thermally rearranges; Ligands

Citation

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31