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Synthetic studies concerning the crinine alkaloid haemultine

Date

Authors

Gao, Yuqian (Nadia)

Ma, Xinghua

Petit, Laurent

Schwartz, Brett

Banwell, Martin

Willis, Anthony

Cade, Ian

Rae, A David

Publisher

CSIRO Publishing

Abstract

The racemic form, (±)-1, of the structure originally assigned to the crinine alkaloid haemultine has been prepared for the first time. A key step involved the conversion of compound (±)-4 into the isomeric cis-C3a-arylhexahydroindole (±)-3 using a Pd0-

Keywords

Keywords: Enantiomerically pure compounds; Intramolecular alder-ene reaction; Natural products; Paraformaldehydes; Pictet-Spengler reactions; Spectroscopic data; Synthetic study; Trifluoroacetic acids; Acetal resins; Enantiomers; Metabolites; Nitrogen compounds

URI

http://hdl.handle.net/1885/70675

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

DOI

10.1071/CH12473

Restricted until

2037-12-31

Downloads

File

Description

01_Gao_Synthetic_studies_concerning_2013.pdf (719.74 KB)