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ortho -Metallated triphenylphosphine chalcogenide complexes of platinum and palladium: synthesis and catalytic activity

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Priver, Steven H
Bennett, Martin
Willis, Anthony
Pottabathula, Srinivas
Lakshmi Kantam, Mannepalli
Bhargava, Suresh Kumar

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Royal Society of Chemistry

Abstract

Treatment of [PtI2(COD)] (COD = 1,5-cyclooctadiene) with 2-LiC6H4P(S)Ph2 gives the complex cis-[Pt{κ2-2-C6H4P(S)Ph2} 2] (1) containing a pair of ortho-metallated triphenylphosphine sulfide rings. The selenium counterpart, [Pt{κ2-2-C 6H4P(Se)Ph2}2] (2),

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Dalton Transactions

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Restricted until

2037-12-31