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Oxidative condensation reactions of (diethylenetriamine)cobalt(III) complexes with substituted bis(pyridin-2-yl)methane ligands

Date

Authors

Zhou, Xiangting

Hockless, David

Willis, Anthony

Jackson, William Gregory

Publisher

Elsevier

Abstract

The synthesis and characterisation of Co(III) complexes derived from a condensation reaction with a central or terminal nitrogen of a dien ligand and the α-carbon of a range of substituted bis(pyridin-2-yl)methane ligands are described. Aerial oxidation

Keywords

Keywords: Amines; Chemical bonds; Cobalt compounds; Condensation reactions; Nuclear magnetic resonance spectroscopy; Oxidation; Single crystals; Synthesis (chemical); X ray crystallography; Aerial oxidation; Complexes; Isomeric products; Ligands; Organometallics 2D NMR studies; Bis(pyridin-2-yl)methane derivatives; Cobalt(III) complexes; Diethylenetriamine; Oxidative C-N bond formation; X-ray structures

URI

http://hdl.handle.net/1885/78266

Collections

ANU Research Publications

Source

Journal of Molecular Structure

Type

Journal article

DOI

10.1016/j.molstruc.2004.12.035

Restricted until

2037-12-31

Downloads

File

Description

01_Zhou_Oxidative_condensation_2005.pdf (418.21 KB)

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