π-Ligand exchange on phosphenium ions: reversible exchange between free and coordinated alkynes in phosphirenium salts

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dc.contributor.authorBrasch, Nicola E
dc.contributor.authorHamilton, Ian
dc.contributor.authorKrenske, Elizabeth
dc.contributor.authorWild, Stanley (Bruce)
dc.date.accessioned2015-12-13T23:12:02Z
dc.date.issued2004
dc.date.updated2015-12-12T08:30:10Z
dc.description.abstractThe rate of reversible alkyne exchange between 1-methyl-1,2,3-triphenylphosphirenium triflate and ethylphenylacetylene, and that of the reverse reaction between 2-ethyl-1-methyl-1,3-diphenylphosphirenium triflate and diphenylacetylene, are independent of
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/87865
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Ligand exchange; Addition reactions; Chemical bonds; Derivatives; Ethylene; Ion exchange; Molecular structure; Nuclear magnetic resonance spectroscopy; Phosphorus compounds; Pyrolysis; Rate constants; Salts; Solvents; Spectrometers; Thermodynamics; Organo
dc.titleπ-Ligand exchange on phosphenium ions: reversible exchange between free and coordinated alkynes in phosphirenium salts
dc.typeJournal article
local.bibliographicCitation.issue2
local.bibliographicCitation.lastpage302
local.bibliographicCitation.startpage299
local.contributor.affiliationBrasch, Nicola E, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHamilton, Ian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationKrenske, Elizabeth, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidBrasch, Nicola E, u9808344
local.contributor.authoruidHamilton, Ian, u9517537
local.contributor.authoruidKrenske, Elizabeth, u4015259
local.contributor.authoruidWild, Stanley (Bruce), u7901996
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.ariespublicationMigratedxPub17332
local.identifier.citationvolume23
local.identifier.doi10.1021/om030607z
local.identifier.scopusID2-s2.0-0942277342
local.type.statusPublished Version

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