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An Unusually Flexible Expanded Hexaamine Cage and Its Cu II Complexes: Variable Coordination Modes and Incomplete Encapsulation

Date

Authors

Qin, Chang
James, Lloyd
Chartres, Jy D
Alcock, Leighton J
Davis, Kimberley J
Willis, Anthony
Sargeson, Alan
Bernhardt, Paul
Ralph, Stephen F

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Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The bicyclic hexaamine "cage" ligand Me 8tricosaneN6 (1,5,5,9,13,13,20,20-octamethyl-3,7,11,15,18, 22-hexaazabicyclo[7.7.7]tricosane) is capable of encapsulating octahedral metal ions, yet its expanded cavity allows the complexed metal to adopt a variety

Description

Keywords

Citation

Source

Inorganic Chemistry

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31