An Unusually Flexible Expanded Hexaamine Cage and Its Cu II Complexes: Variable Coordination Modes and Incomplete Encapsulation
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Qin, Chang
James, Lloyd
Chartres, Jy D
Alcock, Leighton J
Davis, Kimberley J
Willis, Anthony
Sargeson, Alan
Bernhardt, Paul
Ralph, Stephen F
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American Chemical Society
Abstract
The bicyclic hexaamine "cage" ligand Me 8tricosaneN6 (1,5,5,9,13,13,20,20-octamethyl-3,7,11,15,18, 22-hexaazabicyclo[7.7.7]tricosane) is capable of encapsulating octahedral metal ions, yet its expanded cavity allows the complexed metal to adopt a variety
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Inorganic Chemistry
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2037-12-31
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