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Mixed-metal cluster chemistry. 28. Core enlargement of tungsten-iridium clusters with alkynyl, ethynediyl, and butadiynediyl reagents

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Authors

Dalton, Gulliver
Viau, Lydie
Waterman, Susan
Bruce, Michael
Low, Paul J
Roberts, Richard
Willis, Anthony
Koutsantonis, George
Skelton, Brian
White, Allan

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American Chemical Society

Abstract

Reaction of [Wlr3(μ-CO)3(CO)8(η- C5Me5)] (1c) with [W(C=CPh)(CO)3(η-C5H5)] afforded the edge-bridged tetrahedral cluster [W2lr 3(μ4-η2-C2Ph)(μ-CO)(CO) 9(η-C5H5)(η-C5Me 5)] (3) and the edge-bridged trigonal-bipyramidal cluster [W 3lr3(μ4-η2-C 2Ph

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Inorganic Chemistry

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Restricted until

2037-12-31