Gas-phase regiocontrolled generation of charged amino acid and peptide radicals

Date

2006

Authors

Wee, Sheena
Mortimer, Adam
Moran, Damian
Wright, Adam
Barlow, Christopher K
O'Hair, Richard A J
Radom, Leo
Easton, Christopher

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The combined use of advanced mass spectrometry experiments, condensed-phase synthesis of serine and homoserine nitrate ester radical precursors, and high-level ab initio calculations provides a powerful way of examining the fundamental reactivity of radicals derived from peptides.

Description

Keywords

Keywords: amino acid; ester; homoserine; nitric acid derivative; peptide; radical; serine; sodium ion; ab initio calculation; article; dissociation; electron transport; electrospray mass spectrometry; energy; gas; molecular interaction; photolysis; polymerization;

Citation

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b608724h

Restricted until

2037-12-31