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Organometallic complexes for nonlinear optics Part 20. Syntheses and molecular quadratic hyperpolarizabilities of alkynyl complexes derived from (E)-4,4-HCCC6H4N=NC6H4NO2

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Date

2000

Authors

McDonagh, Andrew
Lucas, Nigel
Cifuentes, Marie
Houbrechts, Stephan
Persoons, Andre Pierre
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

The syntheses of the alkyne (E)-4,4′-HCCC6H4N=NC6H4NO 2 (1) and alkynyl complexes LnM{(E)-4,4′-CCC6H4N=NC6H 4NO2} [LnM=trans-[RuCl(dppm)2] (2), Ru(PPh3)2(η-C5H5) (3), Au(PPh3) (4)] are reported. A structural study of 2 reveals E stereochemistry about

Description

Keywords

Keywords: Alkynyl; Cyclic voltammetry; Gold; Nonlinear optics; Quadratic hyperpolarizabilities; Ruthenium; X-ray structure

Citation

URI

http://hdl.handle.net/1885/91193

Collections

ANU Research Publications

Source

Journal of Organometallic Chemistry

Type

Journal article

Book Title

Entity type

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DOI

Restricted until

2037-12-31

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