Organometallic complexes for nonlinear optics Part 20. Syntheses and molecular quadratic hyperpolarizabilities of alkynyl complexes derived from (E)-4,4-HCCC6H4N=NC6H4NO2
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McDonagh, Andrew
Lucas, Nigel
Cifuentes, Marie
Houbrechts, Stephan
Persoons, Andre Pierre
Humphrey, Mark
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Elsevier
Abstract
The syntheses of the alkyne (E)-4,4′-HCCC6H4N=NC6H4NO 2 (1) and alkynyl complexes LnM{(E)-4,4′-CCC6H4N=NC6H 4NO2} [LnM=trans-[RuCl(dppm)2] (2), Ru(PPh3)2(η-C5H5) (3), Au(PPh3) (4)] are reported. A structural study of 2 reveals E stereochemistry about
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Journal of Organometallic Chemistry
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2037-12-31