Synthesis of 1,3-azaphosphol-2-ones. Crystal and molecular structures of [ SP-4-2 ] -dichlorobis(3-phenyl-1,3-dihydrobenzo[1,3]azaphosphol-2-one-P)palladium(II) and its chloro(methyl)platinum(II) analogue

Date

2010

Authors

Bennett, Justine
Doyle, Roy
Lee, Hwi-Young
Lu, Di
Salem, Geoffrey
Speldewinde, David
Tifan, Michelle
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Reaction of secondary phosphine (±)-(2-aminophenyl)phenylphosphine, (±)-app, with PCl5 in toluene gives the hydrochloride salt of the expected chlorophosphine (±)-(2-aminophenyl)chlorophenylphosphine, (±)-acpp.HCl, however, this is not the case with t

Description

Keywords

Keywords: Benzyl bromide; Benzyl derivatives; Crystal and molecular structure; Hydrochloride salts; Hydrophosphination; Low-yield; Magnesium bromide; Methyl iodide; Phenylphosphines; Secondary phosphines; Synthetic routes; Tertiary phosphines; Triphosgene; Hydrocar

Citation

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b916913j

Restricted until

2037-12-31