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gem -Dihalocyclopropanes as building blocks in natural product synthesis

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dc.contributor.authorTaylor, Rebecca
dc.date.accessioned2015-12-13T23:05:58Z
dc.date.available2015-12-13T23:05:58Z
dc.date.issued2003
dc.date.updated2015-12-12T08:03:10Z
dc.description.abstractgem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. These compounds have considerable potential as building blocks in chemical synthesis, especially of natural products. Particular applications include the intramolecular trapping of allylic cations by hateroatom-centered nucleophiles and intermolecular trapping of allylic cations by carbon-centered nucleophiles.
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/85803
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Addition reactions; Catalysis; Chemical bonds; Molecular structure; Olefins; Synthesis (chemical); Building blocks; Dihalocyclopropanes; Electrocyclic ring opening process; Organic compounds
dc.titlegem -Dihalocyclopropanes as building blocks in natural product synthesis
dc.typeJournal article
local.bibliographicCitation.issue6
local.bibliographicCitation.startpage631
local.contributor.affiliationTaylor, Rebecca, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidTaylor, Rebecca, u4020766
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub14461
local.identifier.citationvolume56
local.identifier.doi10.1071/CH02223
local.identifier.scopusID2-s2.0-0345055601
local.type.statusPublished Version

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