One-step synthesis and exploratory chemistry of [5]dendralene

Date

2008

Authors

Bojase-Moleta, Gomotsang
Payne, Alan
Willis, Anthony
Sherburn, Michael

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

(Chemical Equation Presented) Complex polycycles made simple: A practical synthesis of the simplest cross-conjugated pentaene, [5]dendralene, is reported. The hydrocarbon undergoes controllable and atom-efficient domino sequences (see scheme) to generate

Description

Keywords

Keywords: Diels-Alder reactions; Electrocyclic reactions; Hydrocarbons; Polycyclic aromatic hydrocarbons; Reaction kinetics; Synthesis (chemical); 3,4,5 trimethylenehepta 1,6 diene; 3,4,5-trimethylenehepta-1,6-diene; alkene; unclassified drug; article; chemical str Dendralene; Diels-Alder reactions; Domino reactions; Electrocyclic reactions; Hydrocarbons

Citation

Source

Angewandte Chemie International Edition

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/anie.200704470

Restricted until

2037-12-31