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One-step synthesis and exploratory chemistry of [5]dendralene

Date

Authors

Bojase-Moleta, Gomotsang

Payne, Alan

Willis, Anthony

Sherburn, Michael

Publisher

Wiley-VCH Verlag GMBH

Abstract

(Chemical Equation Presented) Complex polycycles made simple: A practical synthesis of the simplest cross-conjugated pentaene, [5]dendralene, is reported. The hydrocarbon undergoes controllable and atom-efficient domino sequences (see scheme) to generate

Keywords

Keywords: Diels-Alder reactions; Electrocyclic reactions; Hydrocarbons; Polycyclic aromatic hydrocarbons; Reaction kinetics; Synthesis (chemical); 3,4,5 trimethylenehepta 1,6 diene; 3,4,5-trimethylenehepta-1,6-diene; alkene; unclassified drug; article; chemical str Dendralene; Diels-Alder reactions; Domino reactions; Electrocyclic reactions; Hydrocarbons

URI

http://hdl.handle.net/1885/49547

Collections

ANU Research Publications

Source

Angewandte Chemie International Edition

Type

Journal article

DOI

10.1002/anie.200704470

Restricted until

2037-12-31

Downloads

File

Description

01_Bojase-Moleta_One-step_synthesis_and_2008.pdf (474.28 KB)

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