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Oxidation chemistry of metal-bonded C4 chains: A combined chemical, spectroelectrochemical, and computational study

Bruce, Michael; Low, Paul J; Costuas, Karine; Halet, J-F; Best, Stephen Peter; Heath, Graham

Description

The known complex {Cp(PPh3)2Ru}2(μ-C≡CC≡C) (3-Ph) and its PMe3- substitution product {Cp(PPh3)(PMe3)Ru}2(μ-C≡CC≡C) (3-Me) have been shown by cyclic voltammetry to undergo a series of four stepwise one-electron oxidation processes. Successive oxi

dc.contributor.authorBruce, Michael
dc.contributor.authorLow, Paul J
dc.contributor.authorCostuas, Karine
dc.contributor.authorHalet, J-F
dc.contributor.authorBest, Stephen Peter
dc.contributor.authorHeath, Graham
dc.date.accessioned2015-12-13T23:27:14Z
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/1885/93226
dc.description.abstractThe known complex {Cp(PPh3)2Ru}2(μ-C≡CC≡C) (3-Ph) and its PMe3- substitution product {Cp(PPh3)(PMe3)Ru}2(μ-C≡CC≡C) (3-Me) have been shown by cyclic voltammetry to undergo a series of four stepwise one-electron oxidation processes. Successive oxi
dc.publisherAmerican Chemical Society
dc.sourceJournal of the American Chemical Society
dc.subjectKeywords: carbon; ruthenium complex; article; metal binding; oxidation; oxidation reduction potential
dc.titleOxidation chemistry of metal-bonded C4 chains: A combined chemical, spectroelectrochemical, and computational study
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume122
dc.date.issued2000
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub26608
local.type.statusPublished Version
local.contributor.affiliationBruce, Michael, University of Adelaide
local.contributor.affiliationLow, Paul J, University of Durham
local.contributor.affiliationCostuas, Karine, Max Planck Institute
local.contributor.affiliationHalet, J-F, CNRS
local.contributor.affiliationBest, Stephen Peter, University of Melbourne
local.contributor.affiliationHeath, Graham, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue9
local.bibliographicCitation.startpage1949
local.bibliographicCitation.lastpage1962
local.identifier.doi10.1021/ja992002t
dc.date.updated2015-12-12T09:49:34Z
local.identifier.scopusID2-s2.0-0034620737
CollectionsANU Research Publications

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