Oxidation chemistry of metal-bonded C4 chains: A combined chemical, spectroelectrochemical, and computational study

Date

2000

Authors

Bruce, Michael
Low, Paul J
Costuas, Karine
Halet, J-F
Best, Stephen Peter
Heath, Graham

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The known complex {Cp(PPh3)2Ru}2(μ-C≡CC≡C) (3-Ph) and its PMe3- substitution product {Cp(PPh3)(PMe3)Ru}2(μ-C≡CC≡C) (3-Me) have been shown by cyclic voltammetry to undergo a series of four stepwise one-electron oxidation processes. Successive oxi

Description

Keywords

Keywords: carbon; ruthenium complex; article; metal binding; oxidation; oxidation reduction potential

Citation

Source

Journal of the American Chemical Society

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31