Organometallic complexes for nonlinear optics Part 23. Quadratic and cubic hyperpolarizabilities of acetylide and vinylidene complexes derived from protected and free formylphenylacetylenes
Date
2001
Authors
Hurst, Stephanie
Lucas, Nigel
Cifuentes, Marie
Samoc, Marek
Luther-Davies, Barry
Asselberghs, Inge
Van Boxel, Roel
Persoons, Andre Pierre
Humphrey, Mark
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier
Abstract
The acetylenes 4-HCCC6H4R [R=CH{OC(O)Me}2 (1), CHO(CH2)3O (2)], ruthenium complexes [Ru(4-CCC6H4R)(PPh3)2(η-C 5H5)] [R=CH{OC(O)Me}2 (3), CHO (4)], [Ru(n-C=CHC6H4R)Cl(dppm)2]PF6 [n=4, R=CHO(CH2)3O (7); R=CHO, n=3 (11), 2 (15)], and [Ru(n-CCC6H4R)Cl(dppm)2
Description
Keywords
Keywords: Acetylide; Electrochemistry; Gold; Hyperpolarizability; Ruthenium; Vinylidene; X-ray structure
Citation
Collections
Source
Journal of Organometallic Chemistry
Type
Journal article
Book Title
Entity type
Access Statement
License Rights
Restricted until
2037-12-31
Downloads
File
Description