Synthesis, crystal structures and magnetic properties of linear and bent trinuclear complexes formed by hexacyanometallates and copper(II) complexes.
Date
2002
Authors
Parker, Richard
Lu, Kevin
Batten, Stuart
Moubaraki, Boujemaa
Murray, Keith
Spiccia, Leone
Cashion, John
Rae, A David
Willis, Anthony
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
The bimetallic trinuclear complexes, [{(tpa)Cu(NC)})2Fe(CN)4]ClO4·6H 2O (1), [{(tren)Cu(NC)})2(Fe(CN)4]ClO)4.4H2O (2), [{Cu(tpa)NC})2Cr(CN)4]ClO4·8H 2O (3) and [{Cu([15]aneN4)NC}2(Cr(CN)4]ClO 4·4H2O (4) [tpa)=tris(2- pyridylmethyl)amine, tren = tris(2-
Description
Keywords
Keywords: Bimetals; Chelation; Chemical bonds; Complexation; Copper compounds; Crystal structure; Ferromagnetism; Magnetic moments; Positive ions; Reduction; Solutions; Synthesis (chemical); Trinuclear complexes; Organometallics
Citation
Collections
Source
Dalton Transactions
Type
Journal article