Skip navigation
Skip navigation
Open Research will be down for maintenance between 8:00 and 8:15 am on Tuesday, December 1 2020.

Comparative study of the reactions of two alkynes and an alkene with chiral cyclopalladated complexes derived from N , N -dimethyl-α-(2-naphthyl)ethylamine and N , N -dimethyl-α-methylbenzylamine: Insertion or cycloaddition.

Gul, Nizamettin; Nelson, John H; Willis, Anthony; Rae, A David


The chiral cyclopalladated complexes containing coordinated 3,4-dimethyl-1-phenylphosphole, DMPP, and an N-donor ligand, (Sc)-l or (Sc)-3, reacted with dimethylacetylene dicarboxylate, DMAD, and diphenylacetylene to produce exclusively the insertion products (Sc)-2, (Sc)-4, (Sc)-5, and (Sc)-6, respectively, although [4+2] Diels - Alder cycloaddition reactions between DMAD or diphenylacetylene and coordinated DMPP were possible. N-Phenylmaleimide underwent [4+2] Diels - Alder cycloaddition to...[Show more]

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Organometallics
DOI: 10.1021/om0200306


File Description SizeFormat Image
01_Gul_Comparative_study_of_the_2002.pdf157.97 kBAdobe PDF    Request a copy
02_Gul_Comparative_study_of_the_2002.pdf158.48 kBAdobe PDF    Request a copy

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator