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Synthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates

Cook, Vernon; Willis, Anthony; Zank, Johann; Wild, Stanley (Bruce)

Description

Diphenylvinylarsine oxide reacts with 1,2-bis (phenylphosphino)ethane in the presence of potassium tert-butoxide to give the anti-Markovnikov product (R*,R*)-(±)/(R*,R**)- 1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane dioxide-1AsO,10AsO, which

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/91692
Source: Inorganic Chemistry
DOI: 10.1021/ic010988d

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