Synthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates

Cook, Vernon; Willis, Anthony; Zank, Johann; Wild, Stanley (Bruce)

doi:10.1021/ic010988d

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Synthesis and resolution of ( R , R )-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates

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Cook, Vernon; Willis, Anthony; Zank, Johann; Wild, Stanley (Bruce)

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Diphenylvinylarsine oxide reacts with 1,2-bis (phenylphosphino)ethane in the presence of potassium tert-butoxide to give the anti-Markovnikov product (R*,R*)-(±)/(R*,R**)- 1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane dioxide-1AsO,10AsO, which

Collections	ANU Research Publications
Date published:	2002
Type:	Journal article
URI:	http://hdl.handle.net/1885/91692
Source:	Inorganic Chemistry
DOI:	10.1021/ic010988d

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Synthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates

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Synthesis and resolution of ( R , R )-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates