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Synthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates

Cook, Vernon; Willis, Anthony; Zank, Johann; Wild, Stanley (Bruce)

Description

Diphenylvinylarsine oxide reacts with 1,2-bis (phenylphosphino)ethane in the presence of potassium tert-butoxide to give the anti-Markovnikov product (R*,R*)-(±)/(R*,R**)- 1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane dioxide-1AsO,10AsO, which

dc.contributor.authorCook, Vernon
dc.contributor.authorWillis, Anthony
dc.contributor.authorZank, Johann
dc.contributor.authorWild, Stanley (Bruce)
dc.date.accessioned2015-12-13T23:22:58Z
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/1885/91692
dc.description.abstractDiphenylvinylarsine oxide reacts with 1,2-bis (phenylphosphino)ethane in the presence of potassium tert-butoxide to give the anti-Markovnikov product (R*,R*)-(±)/(R*,R**)- 1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane dioxide-1AsO,10AsO, which
dc.publisherAmerican Chemical Society
dc.sourceInorganic Chemistry
dc.subjectKeywords: acetonitrile; arsine derivative; copper derivative; decane; dimethylamine; ethane; gold derivative; ligand; metal complex; oxide; palladium; phenyl group; phosphine derivative; potassium derivative; pyrophosphoric acid derivative; silver derivative; vinyl
dc.titleSynthesis and resolution of ( R *, R *)-(�)-1,1,4,7,10,10-hexaphenyl-1,10-diarsa-4,7-diphosphadecane: New ligand for the stereoselective self-assembly of dicopper(I), disilver(I), and digold(I) helicates
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume41
dc.date.issued2002
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub22528
local.type.statusPublished Version
local.contributor.affiliationCook, Vernon, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationZank, Johann, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.startpage1897
local.bibliographicCitation.lastpage1906
local.identifier.doi10.1021/ic010988d
dc.date.updated2015-12-12T09:13:22Z
local.identifier.scopusID2-s2.0-0037041507
CollectionsANU Research Publications

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