Magnetic Exchange in [Mn2(m-O)3(tmtacn)2]2+: Metal-Metal Bonding or Superexchange?
Date
2000
Authors
Delfs, Christopher
Stranger, Robert
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Publisher
American Chemical Society
Abstract
A computational study of the tris-μ-oxo-bridged manganese dimer [Mn2(μ-O)3(NH3)6]2+ as a model for [Mn2(μ-O)3(tmtacn)2]2+ (tmtacn = N',N'',N'''-trimethyl-1,4,7-triazacyclononane) has been undertaken to investigate the magnetic coupling in this complex.
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Keywords: manganese derivative; manganese tris(mu oxo)(n',n'',n''' trimethyl 1,4,7 triazacyclononane); unclassified drug; article; calculation; chemical reaction; energy transfer; geometry; magnetic field; metal binding; molecular interaction
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Inorganic Chemistry
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Journal article
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2037-12-31
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