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Synthesis of [Cu2(Me2[9]aneN2S)2(OH)2](PF6)2, a hydroxo-bridged copper(II) complex of N,N-dimethyl-1-thia-4,7-diazacyclononane (Me2[9]aneN2S). X-Ray structural analysis, magnetic susceptibility, e.p.r. and visible spectroscopy.

Grillo, Vincent; Gahan, Lawrence; Hanson, Graeme; Hambley, Trevor William; Stranger, Robert; Moubaraki, Boujemaa; Murray, Keith


The bis(μ-hydroxo) complex [Cu2(Me2[9]aneN2S)2(OH) 2](PF2)2 (Me2[9]aneN2S = N,N′-dimethyl-1-thia-4,7-diazacyclononane) results after reaction of [Cu(Me2[9]aneN2S)(MeCN)] (PF6) with dioxygen at-78°C in acetonitrile. The complex has been characterized b

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
Source: Australian Journal of Chemistry


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