Synthesis of [Cu2(Me2aneN2S)2(OH)2](PF6)2, a hydroxo-bridged copper(II) complex of N,N-dimethyl-1-thia-4,7-diazacyclononane (Me2aneN2S). X-Ray structural analysis, magnetic susceptibility, e.p.r. and visible spectroscopy.
The bis(μ-hydroxo) complex [Cu2(Me2aneN2S)2(OH) 2](PF2)2 (Me2aneN2S = N,N′-dimethyl-1-thia-4,7-diazacyclononane) results after reaction of [Cu(Me2aneN2S)(MeCN)] (PF6) with dioxygen at-78°C in acetonitrile. The complex has been characterized b
|Collections||ANU Research Publications|
|Source:||Australian Journal of Chemistry|
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