Synthesis of [Cu2(Me2[9]aneN2S)2(OH)2](PF6)2, a hydroxo-bridged copper(II) complex of N,N-dimethyl-1-thia-4,7-diazacyclononane (Me2[9]aneN2S). X-Ray structural analysis, magnetic susceptibility, e.p.r. and visible spectroscopy.

Grillo, Vincent; Gahan, Lawrence; Hanson, Graeme; Hambley, Trevor William; Stranger, Robert; Moubaraki, Boujemaa; Murray, Keith

Synthesis of [Cu2(Me2[9]aneN2S)2(OH)2](PF6)2, a hydroxo-bridged copper(II) complex of N,N-dimethyl-1-thia-4,7-diazacyclononane (Me2[9]aneN2S). X-Ray structural analysis, magnetic susceptibility, e.p.r. and visible spectroscopy.

Date

1999

Authors

Grillo, Vincent

Gahan, Lawrence

Hanson, Graeme

Hambley, Trevor William

Stranger, Robert

Moubaraki, Boujemaa

Murray, Keith

Publisher

CSIRO Publishing

Abstract

The bis(μ-hydroxo) complex [Cu2(Me2[9]aneN2S)2(OH) 2](PF2)2 (Me2[9]aneN2S = N,N′-dimethyl-1-thia-4,7-diazacyclononane) results after reaction of [Cu(Me2[9]aneN2S)(MeCN)] (PF6) with dioxygen at-78°C in acetonitrile. The complex has been characterized b

URI

http://hdl.handle.net/1885/90695

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Full item page

Synthesis of [Cu2(Me2[9]aneN2S)2(OH)2](PF6)2, a hydroxo-bridged copper(II) complex of N,N-dimethyl-1-thia-4,7-diazacyclononane (Me2[9]aneN2S). X-Ray structural analysis, magnetic susceptibility, e.p.r. and visible spectroscopy.

Date

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Abstract

Description

Keywords

Citation

URI

Collections

Source

Type

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until