Towards Detection of a Long-lived Protonated Metal Cation: Generation of GeH2+ Using High-Energy Collisions
Date
2000
Authors
Jackson, Phillip
Diefenbach, Martin
Srinivas, Ragampeta
Schroder, Detlef
Schwarz, Helmut
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-VCH Verlag GMBH
Abstract
A minimal lifetime of microseconds is displayed by the dication GeH2+, which has been detected for the first time as the product of charge-stripping experiments at 8 kV involving [GeH2]+ and O2. Coupled-cluster calculations suggest that XH2+ (X = Si, Ge)
Description
Keywords
Keywords: article; chemical binding; electricity; ligand binding; mass spectrometry; molecular interaction; physics Ab initio calculations; Dications; Germanium; Mass spectrometry
Citation
Collections
Source
Angewandte Chemie International Edition
Type
Journal article
Book Title
Entity type
Access Statement
License Rights
Restricted until
2037-12-31
Downloads
File
Description