Alkoxy radicals in the gaseous phase: β-scission reactions and formation by radical addition to carbonyl compounds
Date
2003
Authors
Rauk, Arvi
Boyd, Russell
Boyd, Susan
Henry, David
Radom, Leo
Journal Title
Journal ISSN
Volume Title
Publisher
NRC Research Press
Abstract
The structures and reactivities of the alkoxy radicals methoxy (CH 3O·), ethoxy (CH3CH2O·), 1-propoxy (CH3CH2CH2O·), 2-propoxy ((CH3)2CHO·), 2-butoxy (CH3CH 2CH(CH3)O·), tert-butoxy ((CH3) 3CO·), prop-2-enoxy (CH2=CHCH2O· ), and but-3-en-2-oxy (CH2
Description
Keywords
Keywords: Addition reactions; Chemical activation; Enthalpy; Ionization; Gaseous phase; Organic compounds; carbonyl derivative; radical; article; calculation; chemical reaction; chemical structure; energy; enthalpy; molecular dynamics; phase transition; polarizatio ß-scission; Addition; Alkoxy; Alkoxyl; B3LYP; Calculaton; Carbonyl; CBS-RAD; Electronic structure; Radical; Thermochemistry
Citation
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Source
Canadian Journal of Chemistry
Type
Journal article