Arene�ruthenium complexes of an acyclic thiolate�thioether and tridentate thioether derivatives resulting from ring-closure reactions
Date
2003
Authors
Shin, Richard
Bennett, Martin
Goh, Lai Yoong
Chen, Wei
Hockless, David
Leong, Weng Kee
Mashima, Kazushi
Willis, Anthony
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
The reaction of [(η6-arene)RuCl2]2 (arene = C6Me6, 1,4-MeC6H4CHMe2) with a large excess of the dianion of bis(2-mercaptoethyl) sulfide, (HSCH2CH2)2S, obtained from deprotonation of the dithiol with freshly prepared NaOMe, gives the deep red, monomeric co
Description
Keywords
Keywords: acetonitrile; alkane derivative; cation; chloride; dithiol derivative; hydrochloric acid; methyl iodide; polycyclic aromatic hydrocarbon; ruthenium; sulfide; sulfur; article; chemical reaction; complex formation; crystal structure; proton transport; ring
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Source
Inorganic Chemistry
Type
Journal article