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Synthesis, molecular structure, and reactivity of neutral and cationic areneosmium(II) complexes with diarylcarbenes as ligands

Weberndorfer, Birgit; Henig, Gerhard; Hockless, David; Bennett, Martin; Werner, Helmut


While the dinuclear compounds [(η6-mes)Os{κ1-OC(O)CF3} (μ-Cl)]2 (2) and [(η6-mes)Os{κ1-OS(O)2 CF3}(μ-Cl)]2 (3), prepared from [(η6-mes)OsCl(η3-C3H5)] (1) and CF3CO2H or CF3SO3H by elimination of propene, are not suitable precursors for the synthes

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Organometallics
DOI: 10.1021/om0207109


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