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Synthesis, molecular structure, and reactivity of neutral and cationic areneosmium(II) complexes with diarylcarbenes as ligands

Weberndorfer, Birgit; Henig, Gerhard; Hockless, David; Bennett, Martin; Werner, Helmut

Description

While the dinuclear compounds [(η6-mes)Os{κ1-OC(O)CF3} (μ-Cl)]2 (2) and [(η6-mes)Os{κ1-OS(O)2 CF3}(μ-Cl)]2 (3), prepared from [(η6-mes)OsCl(η3-C3H5)] (1) and CF3CO2H or CF3SO3H by elimination of propene, are not suitable precursors for the synthes

dc.contributor.authorWeberndorfer, Birgit
dc.contributor.authorHenig, Gerhard
dc.contributor.authorHockless, David
dc.contributor.authorBennett, Martin
dc.contributor.authorWerner, Helmut
dc.date.accessioned2015-12-13T23:11:58Z
dc.date.available2015-12-13T23:11:58Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/87834
dc.description.abstractWhile the dinuclear compounds [(η6-mes)Os{κ1-OC(O)CF3} (μ-Cl)]2 (2) and [(η6-mes)Os{κ1-OS(O)2 CF3}(μ-Cl)]2 (3), prepared from [(η6-mes)OsCl(η3-C3H5)] (1) and CF3CO2H or CF3SO3H by elimination of propene, are not suitable precursors for the synthes
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chelation; Crystallography; Mixtures; Molecular structure; Osmium compounds; Positive ions; Synthesis (chemical); Cationic areneosmium complexes; Diarylcarbenes; Organometallics
dc.titleSynthesis, molecular structure, and reactivity of neutral and cationic areneosmium(II) complexes with diarylcarbenes as ligands
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume22
dc.date.issued2003
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub17291
local.type.statusPublished Version
local.contributor.affiliationWeberndorfer, Birgit, University of Wurzburg
local.contributor.affiliationHenig, Gerhard, University of Wurzburg
local.contributor.affiliationHockless, David, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBennett, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWerner, Helmut, University of Wurzburg
local.bibliographicCitation.issue4
local.bibliographicCitation.startpage744
local.bibliographicCitation.lastpage758
local.identifier.doi10.1021/om0207109
dc.date.updated2015-12-12T08:29:52Z
local.identifier.scopusID2-s2.0-0037450844
CollectionsANU Research Publications

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