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Polyazolyl chelate chemistry. 12. An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

Foreman, Mark; Hill, Anthony; Owen, Gareth; White, Andrew G; Williams, David


The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S″-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of th

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Organometallics
DOI: 10.1021/om030550g


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