Polyazolyl chelate chemistry. 12. An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand
Date
2003
Authors
Foreman, Mark
Hill, Anthony
Owen, Gareth
White, Andrew G
Williams, David
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S″-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of th
Description
Keywords
Keywords: Benzene; Characterization; Chemical bonds; Complexation; Coordination reactions; Hydrogenation; Molecular structure; Organometallics; Reaction kinetics; Styrene; Hydrogenates ethynylbenzene; Hydrotris methimazolyl borato; Ligand; Polyazolyl chelate chemis
Citation
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Source
Organometallics
Type
Journal article