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CP-225,917 and CP-263,114 Synthesis Support Studies: Testing a Radical Cyclization Strategy for Installation of the Side-Chains

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Banwell, Martin; Coster, Mark; Edwards, Alison; Vogtle, Markus

Description

The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/85816
Source: Australian Journal of Chemistry
DOI: 10.1071/CH02244

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