CP-225,917 and CP-263,114 Synthesis Support Studies: Testing a Radical Cyclization Strategy for Installation of the Side-Chains

Date

2003

Authors

Banwell, Martin
Coster, Mark
Edwards, Alison
Vogtle, Markus

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give, via a radical cyclization/allylation sequence, the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).

Description

Keywords

Keywords: Free radical reactions; Materials testing; Molecular structure; Negative ions; Stereochemistry; Synthesis (chemical); Allylation sequence; Allyltributylstannane; Hexabutyldistannane hydride; Lactone; Radical cyclization strategy; Selenocarbonate; Side cha

Citation

URI

http://hdl.handle.net/1885/85816

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH02244

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