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Chemoenzymatic syntheses of (-)-1-deoxymannojirimycin (DMJ) and its naturally occurring 6- O -α-L-rhamnopyranosyl glycoside

Banwell, Martin; Ma, Xinghua; Asano, Naoki; Ikeda, Kyoko; Lambert, John N


Naturally occurring sugar mimetic alkaloids 1-deoxymannojirimycin (DMJ, 1) and 6-0-α-L-rhamnopyranosyl-DMJ were each prepared in a completely stereoselective manner from the cis-1,2-dihydrocatechol 3. The spectral and physical data derived proved an exce

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Organic and Biomolecular Chemistry
DOI: 10.1039/b304063a


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