Chemoenzymatic syntheses of (-)-1-deoxymannojirimycin (DMJ) and its naturally occurring 6- O -α-L-rhamnopyranosyl glycoside
Date
2003
Authors
Banwell, Martin
Ma, Xinghua
Asano, Naoki
Ikeda, Kyoko
Lambert, John N
Journal Title
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Volume Title
Publisher
Royal Society of Chemistry
Abstract
Naturally occurring sugar mimetic alkaloids 1-deoxymannojirimycin (DMJ, 1) and 6-0-α-L-rhamnopyranosyl-DMJ were each prepared in a completely stereoselective manner from the cis-1,2-dihydrocatechol 3. The spectral and physical data derived proved an exce
Description
Keywords
Keywords: Agents; Benzene; Catalysts; Oxidation; Stereochemistry; Synthesis (chemical); Chemoenzymatic synthesis; Deoxymannojirimycin; Rhamnopyradnosyl glycoside; Organic compounds
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Source
Organic and Biomolecular Chemistry
Type
Journal article
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DOI
10.1039/b304063a