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Rethinking The Mesospheres Magnesium Ion Chemistry

Petrie, Simon

Description

High-level quantum chemical calculations address the structural and thermochemical properties of several novel magnesium-containing molecular ions which, we argue, are relevant to the Mg+ chemistry initiated by meteoric ablation in the mesosphere. A model for Mg+ chemistry is evaluated, with results indicating that most ionized magnesium at altitudes of 90 km and below is rapidly hydrated due to the association reactions of the pivotal HOMg+ ion. The implications of this new mechanism,...[Show more]

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/83226
Source: Environmental Chemistry
DOI: 10.1071/EN04070

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