Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)

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Hill, Anthony
Smith, Matthew

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Royal Society of Chemistry

Abstract

The reactions of [MCl4(η-C5H5)] (M = Nb, Ta) with Ph3Sn{HB(mt)3} (mt = methimazolyl) provide structurally characterised complexes of the new chlorobis(methimazolyl)-borate ligand, [MCl3(η-C5H5){κ2- S.S′-HClB(mt)2}].

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Chemical Communications

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Restricted until

2037-12-31