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Imidazole derivatives of binuclear copper (II) and nickel (II) complexes incorporating bis(1,4,7-triazacyclononan-1-yl) ligands

Graham, Bim; Spiccia, Leone; Skelton, Brian; White, Allan; Hockless, David

Description

A series of new binuclear copper (II) and nickel (II) complexes of the macrocyclic ligands bis(1,4,7-triazacyclononan-1-yl)butane (Lbut) and bis(1,4,7-triazacyclononan-1-yl)-m-xylene (Lmx) have been synthesized: [Cu2LbutBr4] (1), [Cu 2Lbut(imidazole)2Br2](ClO 4)2 (2), [Cu2Lmx(μ-OH)(imidazole) 2](ClO4)3 (3), [Cu2L but(imidazole)4](ClO4)4 • H2O (4), [Cu2Lmx(imidazole)4] (ClO4)4 (5), [Ni2 Lbut(H 2O)6](ClO4)4 • 2H2O (6), [Ni2Lbut(imidazole)6](ClO 4)4 • 2H2O (7) and [Ni2L mx (imidazole)4(H2O)2](ClO...[Show more]

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/79745
Source: Inorganica Chimica Acta
DOI: 10.1016/j.ica.2005.06.053

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