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Organometallic macrocyclic chemistry. 6. Chelate-assisted macrocyclization of 4,7,10-trithiatrideca-2,11-diyne

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Hill, Anthony; Rae, A David; Schultz, Madeleine; Willis, Anthony

Description

The diyne 4,7,10-trithiatrideca-2,11-diyne (TTDD) reacts smoothly at room temperature with [Ru(CO)2(PPh3)3] to form [Ru(CO)(PPh3) {η4-S(C2H4SCCMe)2CO-κS}], a cyclopentadienone complex in which the unique sulfur atom is also coordinated to the metal but

CollectionsANU Research Publications
Date published: 2004
Type: Journal article
URI: http://hdl.handle.net/1885/78432
Source: Organometallics
DOI: 10.1021/om0305723

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