Heterobimetallic C 3 complexes through silylpropargylidyne desilylation
Date
2004
Authors
Dewhurst, Rian
Hill, Anthony
Smith, Matthew
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Volume Title
Publisher
Wiley-VCH Verlag GMBH
Abstract
Odd compounds: The study of bimetallic complexes spanned by linear carbon chains was mainly restricted to even-numbered chains. The fluorodesilylation of silylated propargylidynes now provides a range of C3-spanned heterobimetallic complexes based on Ru and either Mo or W (e.g. see picture).
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Keywords
Keywords: Carbon; Molybdenum; Organic compounds; Ruthenium; Tungsten; Desilylation; Linear carbon chains; Bimetals; metal complex; silylpropargylidene; unclassified drug; article; chemical analysis; chemical reaction; complex formation; crystallography; geometry; n Alkynes; Carbynes; Multiple bonds; Ruthenium; Tungsten
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Source
Angewandte Chemie International Edition
Type
Journal article
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Restricted until
2037-12-31
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