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Reactions of μ-alkylidyne complexes with tellurium. Telluroacyl versus μ-telluride formation

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Hulkes, Alexander; Hill, Anthony; Nasir, Bashir; White, Andrew G; Williams, David

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The reactions of heterobimetallic μ-alkylidyne complexes [MFe(μ-CR)(CO)n(η-C5H5)] (M = W, Mo; R = C6H4Me-4 (R1), C6H3Me2-2,6 (R2); n = 5, 6) with elemental tellurium are reported. For [WFe(μ-CR1)(CO)n(η-C5H5)] (n = 5 or 6), the only isolated product

dc.contributor.authorHulkes, Alexander
dc.contributor.authorHill, Anthony
dc.contributor.authorNasir, Bashir
dc.contributor.authorWhite, Andrew G
dc.contributor.authorWilliams, David
dc.date.accessioned2015-12-13T22:39:07Z
dc.date.available2015-12-13T22:39:07Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/77644
dc.description.abstractThe reactions of heterobimetallic μ-alkylidyne complexes [MFe(μ-CR)(CO)n(η-C5H5)] (M = W, Mo; R = C6H4Me-4 (R1), C6H3Me2-2,6 (R2); n = 5, 6) with elemental tellurium are reported. For [WFe(μ-CR1)(CO)n(η-C5H5)] (n = 5 or 6), the only isolated product
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Bimetals; Chemistry; Complexation; Crystal structure; Molecular structure; Tellurium; Ultrasonic applications; Alkylidyne complexes; Telluroacyl; Toluidyne complexes; Ultrasonic activation; Organometallics
dc.titleReactions of μ-alkylidyne complexes with tellurium. Telluroacyl versus μ-telluride formation
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume23
dc.date.issued2004
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub6465
local.type.statusPublished Version
local.contributor.affiliationHulkes, Alexander, Imperial College London
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationNasir, Bashir, University of the Punjab
local.contributor.affiliationWhite, Andrew G, University of Queensland
local.contributor.affiliationWilliams, David, Imperial College London
local.bibliographicCitation.issue4
local.bibliographicCitation.startpage679
local.bibliographicCitation.lastpage686
local.identifier.doi10.1021/om030614n
dc.date.updated2015-12-11T09:46:50Z
local.identifier.scopusID2-s2.0-1442358609
CollectionsANU Research Publications

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