Facile two-step construction of a novel tetrathiamacrotricycle

Date

Authors

Hill, Anthony
Schultz, Madeleine
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Summary: The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cydopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylene- dicarboxylate.

Description

Citation

Source

Organometallics

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31