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Facile two-step construction of a novel tetrathiamacrotricycle

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Hill, Anthony; Schultz, Madeleine; Willis, Anthony

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Summary: The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cydopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylene- dicarboxylate.

dc.contributor.authorHill, Anthony
dc.contributor.authorSchultz, Madeleine
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T22:34:27Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/76121
dc.description.abstractSummary: The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cydopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylene- dicarboxylate.
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Alkylation; Complexation; Crystal structure; Electronic structure; Ethers; Molecular structure; X ray crystallography; Activated alkynes; Cocyclization reactions; Ligands; Tetrathiamacrotricycles; Organometallics
dc.titleFacile two-step construction of a novel tetrathiamacrotricycle
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume24
dc.date.issued2005
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub5012
local.type.statusPublished Version
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSchultz, Madeleine, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue9
local.bibliographicCitation.startpage2027
local.bibliographicCitation.lastpage2029
local.identifier.doi10.1021/om040126v
dc.date.updated2015-12-11T09:21:11Z
local.identifier.scopusID2-s2.0-18644377008
CollectionsANU Research Publications

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