Facile two-step construction of a novel tetrathiamacrotricycle
Date
2005
Authors
Hill, Anthony
Schultz, Madeleine
Willis, Anthony
Journal Title
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Volume Title
Publisher
American Chemical Society
Abstract
Summary: The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cydopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylene- dicarboxylate.
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Keywords
Keywords: Alkylation; Complexation; Crystal structure; Electronic structure; Ethers; Molecular structure; X ray crystallography; Activated alkynes; Cocyclization reactions; Ligands; Tetrathiamacrotricycles; Organometallics
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Source
Organometallics
Type
Journal article
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Restricted until
2037-12-31
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