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Facile two-step construction of a novel tetrathiamacrotricycle

Hill, Anthony; Schultz, Madeleine; Willis, Anthony

Description

Summary: The reactions of [Os(CO)(CA)(PPh3)3] (A = O, S) with 4,7,10-trithiatrideca-2,11-diyne provide cyclopentadienone and cydopentadienethione complexes, the latter affording a novel polythioether macrotricyclic ligand on subsequent treatment with dimethylacetylene- dicarboxylate.

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/76121
Source: Organometallics
DOI: 10.1021/om040126v

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