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Syntheses of pentanuclear group 6 iridium clusters by core expansion of tetranuclear clusters with Ir(CO) 2 (η 5 -C 5 Me 4 R) (R = H, Me)

Randles , Michael; Simpson, Peter; Gupta, Vivek; Fu, Junhong (Nate); Moxey, Graeme; Schwich, Torsten; Criddle, Alan; Petrie, Simon; MacLellan, Jonathan G; Batten, Stuart; Stranger, Robert; Cifuentes, Marie; Humphrey, Mark


Metal cluster core expansion at tetrahedral group 6-group 9 mixed-metal clusters MIr3(μ-CO)3(CO)8(η5- L) (M = W, Mo, L = C5H5; M = Mo, L = C5Me 5) with the iridium capping reagents Ir(CO)2(η 5-L′) (L′ = C5Me5, C 5Me4H) in refluxing toluene afforded

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic401502f


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